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Q.

Define IE1 and IE2. Why IE2 > IE1 for a given atom? Discuss the factors that effect IE of an element.

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Detailed Solution

IE1: The amount of energy required to remove an electron from outermost orbital of isolated neutral gaseous atom is called IE1.
X(g)+IE1X(g)++e
IE2 : The amount of energy required to remove an electron from unipositive gaseous ion is called IE2.
X(g)++IE2X(g)2++e
I.E2 > I.E1 because in unipositive ion number of protons are more than the number of electrons, so the nuclear attraction increases on electrons.
Factors effecting on I.E :
1) Atomic size :
As atomic size increases, I.E value decreases.
As atomic size decreases, I.E value increases.
 I.E α1 Atomic size 
2) Nuclear charge :
As nuclear charge increases, I.E value is also increases. If nuclear charge value decreases,
I.E value decrease.
I.E  Nuclear charge
3) Screening effect :
If Screening effect increases, IE value decreases. If screening effect decreases, I.E value increases.
 I.E α1 Screening effect 
4) Electronic configuration :
Half filled (or) full filled orbitals of an atom are more stable. So they have more I.E. value.

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