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Q.

Describe any two methods of ethylene Give equations for the reactions of ethylene with following.
a) O3 b) Baeyer’s reagent c) water d) HOCl e) O2/Ag at 200°C

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Detailed Solution

PREPARATIONS :
1) Ethyl chloride on heating with alcoholic KOH gives ethylene.
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2) Ethanol is treated with conc. H2SO4 to give ethylene
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PROPERTIES :
a) Reaction with O3 (Ozonolysis) :
Ethylene react with ozone to form two moles of farmaldehyde in presence of Zn/H2O.
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b) With Baeyer’s reagent :
Ethylene is treated with dilute alkaline KMnO4 (Baeyer’s reagent) to form ethylene glycol.
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c) Reaction with water :
Ethylene react with water in presence of concentrated sulphuric acid gives ethyl alcohol.
CH2=CH2+H2OHCH3CH2OH
d) Reaction with HOCl :
Ethylene react with HOCl gives ethylene chlorohydrine
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e) Reaction with O2/Ag at 2000C :
Ethylene react with O2 in presence of Ag to gives ethylene epoxide.
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Describe any two methods of ethylene Give equations for the reactions of ethylene with following.a) O3 b) Baeyer’s reagent c) water d) HOCl e) O2/Ag at 200°C