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Q.

Determine the heat of reaction for this process

FeO(s)+Fe2O3(s)Fe3O4(s)

Given information :

2Fe(s)+O2(g)2FeO(s)          ΔH=544.0kJ4Fe(s)+3O2(g)2Fe2O3(s)    ΔH=1648.4kJFe3O4(s)3Fe(s)+2O2(g)       ΔH=+1118.4kJ

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a

+249-8 kJ

b

- 22.2 kJ

c

-1074.0 kJ

d

+2214.6 kJ

answer is B.

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Detailed Solution

2Fe(s)+O(g)2Fe(s)+O2g; ΔH=544kJ

2Fe2O3(s)4Fe(s)+3O2(g)ΔH=+1648kJ6Fe(s)+4O2(g)2Fe2O3(s);ΔH=2×1118.4kJ

On adding 

2FeO(s)+2Fe2O3(s)2Fe3O4(s);ΔH=44.4kJ2FeO(s)+2Fe2O3(s)2Fe3O4(s);ΔH=22.2kJ

ΔH=1118.4+1648.42+5442 =22.2kJ

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