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Q.

Determine the valency of metal and valence electrons with examples?

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Detailed Solution

Valency of a metal is the number of electrons it usually loses to form a stable ion, and valence electrons are the electrons in its outermost shell. Metals tend to lose outer electrons to reach a noble gas configuration. The number lost is the valency. The electrons available to lose in the outermost shell are the valence electrons. For main-group metals, valency often equals the count of valence electrons; for some transition metals, multiple valencies are possible.

How to find valency 

  • Look at the group number (for groups 1, 2, and 13):
    Group 1 → valency 1; Group 2 → valency 2; Group 13 → usually valency 3.
  • Metals lose electrons → form cations (e.g., Na⁺, Mg²⁺, Al³⁺).
  • Transition metals may show variable valency (Fe²⁺/Fe³⁺, Cu⁺/Cu²⁺).

Valence electrons vs. Valency

ElementElectronic configuration (outer)Valence electronsCommon valencyIon formed
Sodium (Na)…3s111Na⁺
Magnesium (Mg)…3s222Mg²⁺
Aluminium (Al)…3s23p133Al³⁺
Calcium (Ca)…4s222Ca²⁺
Iron (Fe)…3d64s2Generally 2 (4s) with 3d involved2 or 3 (variable)Fe²⁺, Fe³⁺
Copper (Cu)…3d104s11 (often)1 or 2Cu⁺, Cu²⁺

Steps to determine quickly

  1. Write or recall the element’s group and outer electrons.
  2. If it is a metal, count how many electrons it tends to lose to reach the nearest noble gas.
  3. That number is the valency. Those outer electrons are the valence electrons.
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