Q.

Determine the values of equilibrium constant Kc and ΔG or the following reaction :
Ni(s)+2Ag+(aq)Ni2+(aq)+2Ag(s)E=1.05V1F=96500Cmol1

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answer is 1.

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Detailed Solution

According to the formula
ΔG=nFE=2×96500×1.05 or ΔG=202650Jmol1=202.65KJmol1 Now ΔG202650JMol1 R=8.314J/Mol/K,T=298K
logK=ΔG2.303RT
or logK=2026502.303×8.314×298
logK=2026505705.84831=35.52 K= Antilog of 35.52 K=0.35×107

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