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Q.

Diborane is a potential rocket fuel which undergoes combustion according to the reaction,  B2H6(g)+3O2(g)B2O3(s)+3H2O(g) from the following data, the enthalpy change for the combustion of diborane will be:

2B(s)+32O2(g)B2O3(s); ΔH=1273kJ

H2(g)+12O2(g)H2O(l); ΔH=286kJ

H2O(l)H2O(g)   ΔH=44kJ

2B(s)+3H2(g)B2H6(g); ΔH=46kJ

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a

2079 kJmol1

b

2045kJmol1

c

1091 kJmol1

d

762kJmol1

answer is C.

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Detailed Solution

 enthalpy change, ΔH=ΔHB3O3(s)+3ΔHH2O(g)ΔHB2O6(g)ΔHf0 of O2=0

ΔH=[1273+3(242)]36KJ/mol

1273286×3+44×346 =2045kJ/mol

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