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Q.

Dow's process :

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a

involves purification of copper

b

involves extraction of magnesium

c

gives metal chloride as product

d

gives pure Na as product

answer is B.

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Detailed Solution

Dow's process is an industrial method used for extracting magnesium from seawater. This method involves a series of steps starting with seawater, which is first concentrated through natural solar evaporation. Once concentrated, the seawater undergoes a treatment with slaked lime (calcium hydroxide). This treatment helps to precipitate out magnesium hydroxide (Mg(OH)₂), which is a key intermediate compound in the extraction process of magnesium.

Next, the magnesium hydroxide is subjected to heat in a stream of hydrochloric acid (HCl), which reacts to produce magnesium chloride (MgCl₂). This step is crucial as magnesium chloride is the primary compound that will later be used to produce magnesium metal. The magnesium chloride solution, known as the brine, contains a mixture of different salts, including magnesium chloride, sodium chloride (NaCl), and calcium chloride (CaCl₂). In Dow's process, the brine is typically composed of approximately 35% MgCl₂, 50% NaCl, and 15% CaCl₂.

Once the magnesium chloride solution is prepared, the next step in Dow's process involves the electrolysis of MgCl₂. Electrolysis is a method where an electric current is passed through the molten magnesium chloride, causing the magnesium to be separated from chlorine and collected as metal. This process yields high-purity magnesium metal, which can then be used in various industries, including the production of lightweight materials for automobiles and aerospace, as well as in the production of alloys.

In summary, Dow's process for magnesium extraction involves several key steps: concentration of seawater, treatment with slaked lime, reaction with hydrochloric acid to form magnesium chloride, and electrolysis of the magnesium chloride to produce magnesium metal. Dow's process is a widely recognized and efficient method for extracting magnesium from seawater, providing an essential resource for various industrial applications.

Conclusion

To summarize, the Dow's process is an effective technique for the extraction of magnesium, starting from seawater and using various chemical treatments and electrolysis. The process is well-known for its ability to produce high-quality magnesium in an energy-efficient manner. Therefore, Dow's process remains a significant method in the industrial production of magnesium.

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