Q.

Dry air was passed successively through a solution of 5g of a solute in 80g water and then through pure water. The loss in weight of solution was 2.50g and that of pure solvent was  0.04g. The molecular weight of the solute would be 

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a

70.31

b

703.1

c

7.143

d

7031

answer is A.

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Detailed Solution

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Loss of weight of solution  ps
Loss of weight of solvent  p0ps
p0psps=LossofweightofsolventLossofweightofsolution
or   XB=LossofweightofsolventLossofweightofsolution
WB/MBWA/MA=0.042.5WBMB×MAWA=0.042.5
Or  MB=2.5×WB×MA0.04×WA=2.5×5×180.04×80=70.31
 

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Dry air was passed successively through a solution of 5g of a solute in 80g water and then through pure water. The loss in weight of solution was 2.50g and that of pure solvent was  0.04g. The molecular weight of the solute would be