Q.

During melting of an ice slab at 273 K at 1 atm pressure:

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a

Positive work is done by the ice-water system on the atmosphere

b

Negative work is done on the ice-water system by the atmosphere

c

The entropy of the ice-water system decreases

d

The internal energy of the ice-water system increase

answer is D.

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Detailed Solution

In the melting process of the slab of ice at the temperature of 273 K and atmospheric pressure, it changes into water after little increase in temperature. 

Here,

Internal energy of water > Internal energy of ice. 

So, internal energy of ice-water system increases. 

With this volume decreases and work done become positive.

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