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Q.

During the electrolysis of aqueous cupric chloride using inert electrodes, pH

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a

Progressively increases

b

Progressively decreases

c

Remains constant

d

Initially increases and then decreases and finally remains constant

answer is A.

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Detailed Solution

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aq. CuCl2pH<7
Cathode : Cu2++2eCu
Anode : 2ClCl2+2e
As the electrolysis progresses concentration CuCl2 decreases. 
The solution becomes richer in water, pH increases.

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