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Q.

During the electrolysis of fused carnalite, MgCI2 is decomposed to liberate Mg at cathode and not KCI to liberate the Kat cathode. This is because of:

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a

lower decomposition voltage of MgCI2 than that of KCl

b

higher decomposition voltage of MgCI2 than that of KCl

c

higher melting point of MgCI2 than KCl

d

none of the above

answer is A.

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Detailed Solution

In contrast to KCI, magnesium chloride would have released cathode during the electrolysis of fused carnalite, MgCI2 is broken down to release Mg at the cathode. This is due to MgCI2’s lower decomposition voltage when compared to KCl.

Hence the correct option is A.

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