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Q.

During the kinetic study of the reaction, 2A + B  C + D, following results were obtained: 

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Based on the above data which one of the following is correct? 

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a

rate = k[A][B]2

b

rate = k[A]2[B]2

c

rate = k [A]2[B]

answer is D.

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Detailed Solution

In case of (II) and (III), keeping concentration of [A] constant, when the concentration of [B] is doubled, the rate quadruples. Hence it is second order with respect to B. in case of I & IV keeping the concentration of [B] constant. When the concentration of [A] is increased four times, rate also increases four times. Hence, the order with respect to A is one, hence Rate = k [A][B]2   

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During the kinetic study of the reaction, 2A + B → C + D, following results were obtained:      Based on the above data which one of the following is correct?