Q.

During the melting of a slab of ice at 273 K at atmospheric pressure

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a

Positive work is done by ice-water system on the atmosphere

b

The internal energy of the ice-water system decreases

c

Positive work is done on the ice-water system by the atmosphere

d

The internal energy of the ice-water system remains same

answer is B.

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Detailed Solution

There is a decrease in volume during melting on an ice slab at 273K. Therefore,
negative work is done by ice-water system on the atmosphere or positive work is
done on the ice-water system by the atmosphere. Hence option (b) is correct.
Secondly heat is absorbed during melting (i.e ΔQ is positive) and as we have seen,
work done by ice-water system is negative (ΔW is negative). Therefore, from first
law of thermodynamics ΔU=ΔQΔW.

Change in internal energy of ice-water system, ΔU will be positive or internal
energy will increase

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