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Q.

During the Qualitative analysis of salt with cation Y²⁺ , addition of a reagent (X) to alkaline solution
of the salt gives a bright red precipitate. The reagent (X) and the cation (Y²⁺) present respectively are:

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a

$Nessler's reagent and {Hg}^{2 +}$

b

$Dimethylglyoxime and {Ni}^{2 +}$

c

$Nessler's reagent and {Ni}^{2 +}$

d

$Dimethylglyoxime and {Co}^{2 +}$

answer is A.

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Detailed Solution

${Ni}^{2 +} + {DMG}^{-} \to \underset{(Bright red precipitate)}{[Ni (DMG)_{2}] ↓}$

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