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Q.

During the race of complex compounds, finish line is fixed by achieving EAN value equal to the atomic number of corresponding inert gas. Then which of the following complex is present at the finish line?

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a

Fe3Fe(CN)62

b

Mn(CO)5

c

K4Fe(CN)6

d

CoNO264

answer is C.

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Detailed Solution

K4[Fe((N)6]- will be present at the finish line because its EAN value is 36.
If n, Z, and x are the numbers of ligands, then the metal ion's atomic number and oxidation state are as follows:

EAN=z-x+2nL [L=1 for mono di tetra ligand L=2 for bi di tetra ligand] 

For,  K4[Fe((N)6]-

x=+2z=26, N=6, L=1

EAN =26-2+(2×1×6)

EAN=24+12=36

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