Q.

During the reaction of permanganate with thiosulphate, the change in oxidation of manganese occurs by value of 3. Identify which of the below medium will favour the reaction

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a

Both aqueous acidic and neutral

b

Both aqueous acidic and faintly alkaline

c

Aqueous acidic

d

Aqueous neutral

answer is A.

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Detailed Solution

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The reaction of potassium permanganate with sodium thiosulfate gives sodium sulfate, potassium sulfate and insoluble manganese dioxide

KMnO4​+Na2​S2​O3​.5H2​O→Na2​SO4​+K2​SO4​+MnO2

Mn+7O4 Mn+4O2

Change in oxidation state=3

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