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Q.

E0 for two reactions are given below: Cr+3+3eCr,E0=0.74V;OCl+H2O+2eCl+2OH1,
E0 = 0.94V. What will be the E0 for 3OCl+2Cr+3H2O2Cr+3+3Cl+6OH

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a

–1.68 V

b

–0.20V

c

1.68 V

d

+0.20 V

answer is B.

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Detailed Solution

ECell=Ecathode0-Eanode0

=0.94-(-0.74)=1.68V

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E0 for two reactions are given below: Cr+3+3e−→Cr,E0=−0.74V;OCl−+H2O+2e−→Cl−+2OH−1,E0 = 0.94V. What will be the E0 for 3OCl−+2Cr+3H2O→2Cr+3+3Cl−+6OH−