Q.

E01/2Cl2|Cl-=+1.36V .The single electrode potential of Pt, Cl2 (1atm)|Cl- (0.1 M) is

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a

–1.42V

b

+1.36V

c

–1.36V

d

+1.42V

answer is C.

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Detailed Solution

Platinum is an electrode at which Cl2(1atm)|Cl- at concentration of Cl-=0.1M
Here 12Cl2Cl-
Given:  E1/2Cl2|Cl-0=+1.36 V ,n=1
By Nernst equation at 250C

ECl2|Cl- =ECl2|Cl-0-0.05911log10[Cl-]             =+1.36-0.0591log10 10-             =+1.36+0.0591             =+1.42V 

Therefore option C is correct.
 

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