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Q.

E0Al3+ / Al=-1.66V and E0Tl3+ / Tl=-1.26V.

Then which of the following statements is correct?
A) Aluminium has high tendency to form Al3+ ions in aqueous solution.
B) Tl3+ is unstable in aqueous solution
C) Tl3+ is a powerful oxidising agent
D) Al is a powerful reducing agent

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a

Only A,B

b

Only C,D

c

Only A,C,D

d

A,B,C,D

answer is D.

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Detailed Solution

  • The standard electrode potentials of the two given half cells, aluminium has a high tendency to formAl3+(aq) ions as compared toTl3+
  • Tl3+ is unstable in solution and it acts as a powerful oxidizing agent. Aluminium being able to form  +3 ions easily, is more electropositive than thallium.
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