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Ease of esterification of the following alcohols
I) CH₃CH₂OH
II) (CH₃)₂CHOH
III) (CH₃)₃COH with HCOOH is

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An Intiative by Sri Chaitanya

I = II = III

II < I < III

III < II < I

I < II < III

answer is B.

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Detailed Solution

Larger is the size of alcohol, more difficult it will be for an alcohol to attack the carbonyl group of protonated acid and there is too much steric crowding in a tetrahedral complex.

Hence primary alcohol reacts faster.

Therefore, III < II < I

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