Ebullioscopic and cryoscopic constant for water are 0.52 K-kg-mole and 1.86 K-kg-mole respectively. If on dissolving 5 g of ${\mathrm{Na}}_2{\mathrm{SO}}_4$in $45\mathrm{g}$of ${\mathrm{H}}_2\mathrm{O}$ cause freezing point to be decreased to -3. 72° C. Calculate van't Hoff coefficient of ${\mathrm{Na}}_2{\mathrm{SO}}_4$: