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Q.

Ecell°=1.1 V  for Daniel cell.  Which of the following expressions are correct description of state of equilibrium in this cell? 

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a

1.1=KC

b

2.303RT2FlnKC=1.1

c

logKC=2.20.059

d

logKC=1.1

answer is C.

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Detailed Solution

ΔG°=2.303RTlogKc

nFEcello=2.303RTlogKc

2×F×1.1=2.303RTlogKc

logKc=2×F×1.12.303RT

logKC=2.20.059 (2.303RTF=0.059)

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