Q.

Edge length of NaCl unit cell is 552 pm. Then which are correct statements

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a

radii of Na+ and Cl ion will be 95 pm and 181 pm

b

nearest distance between two Na+ ions is 2762pm

c

nearest distance between Cl ions is952pm

d

distance between Na+ and Cl ions is 276 pm

answer is A, B, C.

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Detailed Solution

For NaCl a=2rc+2ra;a=2rc+2ra=552pm
rc+ra=276pm,rc/ra=0.52;rc/ra=95/181
Nearest distance between two Na+ ions is the
distance from body centre to edge centre is
i.e, (276)2+(276)2=2762pm.

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