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Q.

Edge length of NaCl unit cell is 552 pm. Then which are correct statements

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a

Radii of  Na+ and  Cl  ion will be 95 pm and 181 pm

b

Nearest distance between  Cl ions is  952pm

c

Distance between  Na+ and  Cl ions is 276 pm

d

Nearest distance between two Na+ ions is  2762 pm

answer is A, B, C.

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Detailed Solution

 For NaCl   a(edge length)=2rc++2ra-=552pm;

rc++ra-=276pm,rc+/ra-=0.52;rc+/ra-=95/181

Nearest distance between two Na+ ions is the distance from body center to edge center is

i.e.2762+2762=2762pm.

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