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Q.

 EFe3+/Fe2+0=0.772V;EFe2+/Fe0=0.44V
Then EFe3+/Fe0 will be

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a

0.332 V

b

-0.332 V

c

-0.036 V

d

-0.108 V

answer is C.

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Detailed Solution

Fe3++e Fe2+   E0=+0.772V......1Fe2++2e Fe   E0=+0.44V......2Fe3++3e Fe   E0=?ΔG=ΔG1+ΔG2

-nE = -n1E1 -n2E2

nE = -n1E1 + n2E2

E=10.772+20.443=0.036V

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