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Q.

Eight mole of a gas AB3 attain equilibrium in a closed container of volume 1 dm2AB3A2(g)+3B2(g). If at equilibrium 2 mole of A2 are present then, equilibrium constant is:

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a

36 mol2L-2

b

72mol2L-2

c

3 mol2L-2

d

27 mol2L-2

answer is D.

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Detailed Solution

 t=0Ar equilibrium: 2AB38(8-a)A20a/2(g)+3B203a2(g)
Thus, KC=A2B23AB32; Alsoa2=2 a=4
AB3=41;A2=21;B2=61
Thus, Kc=2×6342=27mol2L2

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