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Q.

Electrochemical equivalent of a divalent metal is 3×104gm/coulomb . The approximate atomic weight of the metal is

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a

58

b

107.8

c

63.6

d

55.9

answer is C.

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Detailed Solution

Electro chemical equivalent  is the mass deposited by passing charge of one coloumb

Eq.wt of  the substance  deposits by passing charge of 96500 coloumbs

96500Coloumbs(1F)E

1C?             

 e=EF,E=e×F ( electro chemical equivalent (e)= EF

e=EFE=e×F

                       =3×104×96500

                       =28.95 g.

At.wt=E×valency                       Equivalent weight=Atomicweightvalency

            =28.95×2  

            =57.958g     

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