Q.

Electron gain enthalpy with negative sign of fluorine is less than that of chlorine due to:

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a

High ionization enthalpy of fluorine

b

Smaller size of chlorine atom

c

Smaller size of fluorine atom

d

Bigger size of 2p orbital of fluorine 

answer is C.

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Detailed Solution

F-atom has smaller size and incoming  e feels more repulsion from already present e in F-atom hence, electron gain enthalpy with negative sign (electron affinity) of fluorine is less than that of chlorine.

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Electron gain enthalpy with negative sign of fluorine is less than that of chlorine due to: