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Q.

Emf of the cell,Zn(s)|Zn2+(102M)||Cu2+(1M)|Cu(s) is 0.0886V. Equilibrium constant for the above reaction at 298K will be

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a

101

b

100

c

1          

d

10

answer is C.

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Detailed Solution

Zn+Cu2+Zn2++Cu

Ecell=Ecell00.05912log[Zn2+][Cu2+]

0.0886=Ecell00.05912log1021

0.0886=Ecell0+0.0591

0.0886=Ecell0+0.0591

Ecell0=0.08860.0591=0.0295

0.0295=0.05912logkc.

logkc=1    kc=101=10

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