Q.

Enthalpy for the reaction

Ag+(aq)+Br(aq)AgBr(s) is 90kJ

Magnitude of enthalpy of formation of Ag+ (aq) and Br- (aq) are in the ratio 5 : 6. Formation of Ag+(aq) is an endothermic process whereas formation of Br- is an exothermic process. Enthalpy of formation of AgBr is -110 kJ/mole. Calculate the enthalpy of formation of Ag+(aq) in kJ/mol

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Detailed Solution

Ag+(aq)+Br(aq)AgBr(s); ΔH=90kJ

ΔHfAg+(aq)ΔHfBr(aq)=56=56.......(i)

ΔHfAgBr=110kJmol1

90=110ΔHfAg++ΔHfBr.....(ii)

 Solving eqns. (i) and (ii), we get 

ΔHfAg+=100kJmol1

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