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Q.

Enthalpy of Hydrogenation of one mole of benzene to cyclohexane is
(Resonance energy of benzene =150.4 kJ/mol )
(enthalpy of Hydrogenation of cyclohexene =119.5 kJ/mol )

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a

208.1 kJ/mol

b

358.1 kJ/mol

c

+150.4 kJ/mol

d

269.9 kJ/mol

answer is A.

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Detailed Solution

The Hydrogenation of cyclohexene forms cyclohexane

C6H10+H2C6H12

As the breaking of 1 C=C Bond and the formation of 2 C-H Bonds has a net release of 119.5 kJ/mol, 

So, in the case of benzene, 3 C=C bonds is hydrogenated by

3×119.5 kJ/mol=358.5 kJ/mol

Since, benzene has resonance energy, the enthalpy change of hydrogenation is:

358.5 kJ/mol150.4 kJ/mol=208.1 kJ/mol

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