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Q.

Enthalpy of sublimation of iodine is 40calg1at2000C . If specific heat of  I2(s)andI2(vap)  are 0.055 and 0.031 cal  g1K1 respectively, then enthalpy of sublimation of iodine at  2500C in cal  g1 is ______ [nearest integer]

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answer is 39.

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Detailed Solution

ΔCp=H2H2T2T1   I2(s)I2(g),   ΔI1=40  cal/ga2000C ΔH2=ΔH1+CPr(T2T1)   =40+(0.0310.055)×(250200) =401.2       =38.8  cal/gram

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