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Q.

Equal volumes of 0.5N acetic and 0.5N sodium acetate are mixed. What is the pH of resultant solution? (pKa of acetic acid=4.75)

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a

4.85

b

4.65

c

4.75

d

7.0

answer is C.

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Detailed Solution

Given concentration of acetic acid, 

[CH3COOH]=0.5N

Concentration of sodium acetate, 

[CH3COONa]=0.5N

pKa of  CH3COOH=4.75

Using Henderson Hasselbalch equation

pH=pKa+log[CH3COONa][CH3COOH]

 pH=4.75+log0.50.5

So,pH= 4.75+log1=4.75+0

=4.75

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