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Q.

Equal volumes of 1 M HNO3   and 1 M H3PO4 are neutralized by dilute NaOH solution. If xand y K.cals are the heats liberated in the neutralization of HNO3 and H3PO4respectively, the relation between x and y (assume H3PO4 is completely ionized)

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a

x = 3y

b

3x = y

c

2x = y

d

x = y

answer is C.

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Detailed Solution

HNO3+NaOHNaNO3+H2O;H=-xK.Cal

H3PO4+3NaOHNa3PO4+3H2O;H=-yK.Cal

H=3x

x=y3

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