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Q.

Equal volumes of following solutions are mixed. In which case the pH of resulting solution will be average value of pH of two solutions?

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a

Aqueous HCl of pH= 2, aqueous HCl of pH= 4

b

Aqueous NaOH of pH = 12, aqueous NaOH of pH= 10

c

Aqueous CH3COOH of pH= 5, aqueous NH3 of pH = 9. [Ka (CH3COOH) = Kb (NH3)]

d

Aqueous HCl of pH= 2, aqueous NaOH of pH= 12

answer is A, D.

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Detailed Solution

(a) HCl102×V+NaOH102×VNaCl+H2O -            -             pH = 7

(d) pH=9+52=7.0

Correct option is A, D

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