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Q.

Equilibria, $X ⇌ 2 Y$ and $Z ⇌ P + Q$ are established with 1 mole of X and Z taken initially in separate vessels with equilibrium pressures of 1 atm and 36 atm respectively If the degree of dissociations are same, then $K_{p_{2}} = n K_{p_{1}}$ . What is the value of ‘n’ ?

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answer is 9.

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Detailed Solution

$\frac{K_{P_{1}}}{K_{P_{2}}} = \frac{4 P_{1}}{P_{2}} = \frac{4 \times 1}{36} = \frac{1}{9} \Rightarrow K_{P_{2}} = 9 K_{p_{1}}$

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Equilibria, X⇌2Y and Z⇌P+Q are established with 1 mole of X and Z taken initially in separate vessels with equilibrium pressures of 1 atm and 36 atm respectively If the degree of dissociations are same, then Kp2=nKp1. What is the value of ‘n’ ?