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Q.

Equimolal solutions of  KCl and compound  X in water show depression in freezing point in the ratio of  4:1. Assuming KCl to be completely ionized, the compound X  in the solutions must:

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a

Dissociate to the extent of 50%

b

Hydrolyze to the extent of 80% 

c

Trimerise to the extent of 75%

d

Dimerise to the extent of 50%

answer is D.

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Detailed Solution

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For equimolal solution 
ΔTf1ΔTf2=i1i2 then  41=2i2
i2=0.5 i.e association 
i=1α+αn
 

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