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Q.

Equimolal solutions of NaCl, BaCl2 and Na3PO4 are prepared in water, then correct statements are

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a

Freezing point of NaCl solution is –2°C if freezing point of BaCl2 solution is –3°C

b

Freezing point of Na3PO4 is –4°C if freezing point of BaCl2 is –3°C

c

Elevation in boiling point for BaCl2 solution is 1.5 times higher than NaCl solution

d

Elevation in boiling point for NaCl is half of Na3PO4 solution

answer is A, B, C, D.

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Detailed Solution

‘m’ for NaCl; BaCl2 and Na3PO4 is same i (for NaCl) = 2 ; i (for BaCl2) = 3
ΔTf1=2×Kf×m;ΔTf2=3×Kf×m
Hence (1) is correct answer
For Na3PO4 (i = 4) and for BaCl2 (i = 3)
∴ Freezing point is –4°C and –3°C
For BaCl2 (i = 3) and for NaCl (i = 2)
∴ Elevation in boiling point for BaCl2 is 1.5 times higher than NaCl solution and for NaCl
(i = 2)
Na3PO4 (i = 4)
Elevation in BP for NaCl is half of Na3PO4 solution

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