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Q.

Equivalent conductance at infinite dilution of Ca+2 and PO43 are ‘X’ mho cm2 geq1 and ‘Y’ mho cm2 geq1 respectively. Molar conductance at infinite dilution of Ca3PO42 is equal to ……. mho cm2 mole-1

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a

2X+3Y4

b

2X+3Y

c

6X+6Y

d

2X+Y

answer is D.

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Detailed Solution

ΛCa3PO42eq=ΛCa+2eq+ΛPO43eq=X+YΛeqo×valency=ΛmoΛmo=6X+Yvalency  of  Ca3PO42=6Net  charge  of  cation  or  anionCa3PO423Ca+2+2PO43

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