Q.

Equivalent conductance of 1 M propanoic acid is 10 ohm1cm2eq1 and that at infinite dilution 200 ohm1cm2eq1 pH of the propanoic  acid  solution is

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a

7

b

1.3

c

6.8

d

3.3

answer is C.

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Detailed Solution

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Propanoic acid is weak acid , its degree of ionization (α) is calculated as 

α  =(equivalent conductance at given concentration)ec(equivalent conductance at infinite dilution) eo=10200=0.05

[H+]== 1 ×0.05= 0.05 C= Concentration  pH= -log [H+]       =-log (0.05) pH = 1.3

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