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Q.

Equivalent conductance of BaCl2, H2SO4 and HCl are x1, x2 and x3 S cm2 equiv–1 at infinite dilution. If specific conductance of saturated BaSO4 solution is y S cm–1, then Ksp of BaSO4 is

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a

103y2x1+x2−2x3

b

106y3x1+x2−2x32

c

106y22x1+2x2−2x32

d

x1+x2−2x3106y2

answer is C.

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Detailed Solution

equivalent conductance = 2(x1+x2-x3)

Molarity = 1000×y2(x1+x2-x3)

Ksp = 106y24(x1+x2-x3)2

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Equivalent conductance of BaCl2, H2SO4 and HCl are x1, x2 and x3 S cm2 equiv–1 at infinite dilution. If specific conductance of saturated BaSO4 solution is y S cm–1, then Ksp of BaSO4 is