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Q.

Equivalent conductivity of a weak acid HA at infinite dilution is 390 cm2 eq-1 . Conductivity of 1x 10-3  N HA solution is 4.9 x 1 -5 S cm--1 Calculate the extent of dissociation and dissociation constant of the acid. 

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Detailed Solution

Equivalent conductivity of 1 x 10-3 N HA solution (AM) = k/ normality.
λc = 4.9x10-5  x1000 1 x 10-3 = 49 S cm2 eq-1
Equivalent conductance at infinite dilution (A0 ) = 390 S cm2 wq-1 
Extent of dissociation = α = λcλ0= 49390 = .126
Dissociation constant of acid = Cα2 = 1 x 10 -3(0.126)2 = 1.5 x 10-5mol L-1   

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