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Q.

Equivalent weight of K2Cr2O7 in the following reaction is 

Cr2O72- + Fe2+  Fe3++  Cr3+

(M = molar mass of K2Cr2O7)

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a

M6

b

M5

c

M3

d

M4

answer is B.

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Detailed Solution

 

Question Image

 

 

 

 

 

 

 

Balance Cr oxidation number of Cr-atom on each side

Thus, equivalent weight of

K2Cr2O7 = molar  masschange in ox.state = M6

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Equivalent weight of K2Cr2O7 in the following reaction is Cr2O72- + Fe2+ → Fe3++  Cr3+(M = molar mass of K2Cr2O7)