Q.

Equivalent weight of MnO4 in acidic, neutral and strong basic media are in ratio of:

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a

5:3:1

b

3:5:15

c

3:15:5

d

5:1:13

answer is A.

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Detailed Solution

i).  MnO4ΘMn2+(acidic)Ew=Mw5

ii).  MnO4ΘMnO2(neutral)Ew=Mw3

iii).  MnO4ΘMnO42(basic)Ew=Mw1

Ratio is 15:13:11=3:5:15

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