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Q.

Ester is not formed in the following reaction. Identify the suitable reaction

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a

${CH}_{3} COOH + C_{2} H_{5} OH \overset{H^{+}}{\to}$

b

$C_{2} H_{5} OH + {CH}_{3} {COOCOCH}_{3} \overset{}{\to}$

c

${CH}_{3} {CH}_{2} OH + {CH}_{3} COCl ⟶$

d

$C_{2} H_{5} {OC}_{2} H_{5} + {CH}_{3} Cl ⟶$

answer is D.

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Detailed Solution

${CH}_{3} COOH + C_{2} H_{5} OH \overset{H^{+}}{\to} {CH}_{3} {COOC}_{2} H_{5} + H_{2} O$
$C_{2} H_{5} OH + {CH}_{3} {COOCOCH}_{3} \to {CH}_{3} {COOC}_{2} H_{5} + {CH}_{3} COOH$
${CH}_{3} {CH}_{2} OH + {CH}_{3} COCl ⟶ {CH}_{3} {CH}_{2} {COOCH}_{3} + HCl$
$C_{2} H_{5} {OC}_{2} H_{5} + {CH}_{3} Cl ⟶ C_{2} H_{5} {OCH}_{3} + C_{2} H_{5} Cl$

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Ester is not formed in the following reaction. Identify the suitable reaction