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Q.

Esterification reaction given as RCOOH(aq)+R1OH(aq)RCOOR(aq)1+H2O(l) .At same temperature diluting the equilibrium reaction with more water, then what change will be observed compared with equilibrium values?

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a

Increase the number of moles of ester 

b

Increase the number of moles of acid

c

Increase the value of equilibrium constant

d

No effect on equilibrium as water is pure liquid for which concentration is constant.

answer is B.

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Detailed Solution

 Reaction quotient =RCOOR1[H2O][RCOOH]R1OHi

With dilution (by adding water), product side concentration increases and rb dominating than rf ,  (temporarily) . So equilibrium position will shifts from right to left. therefore no of moles of   RCOOH increases.

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