Q.

Etard reaction in the following is :

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a

oxidation of toluene is benzaldehyde by chromyl chloride

b

oxidation of toluene of benzaldehyde of alkaline KMnO4

c

dry distiIlation of calcium benzoate

d

reaction of benzene with Cl2 in the presence of UV light

answer is A.

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Detailed Solution

Toluene is transformed into benzaldehyde by chromyl chloride. The Etard reaction is the name of this process. Carbon disulfide is employed as the solvent. The methyl group is changed into a chromium complex by chromium chloride. The equivalent aldehyde is produced by this compound on acid hydrolysis.
C6H5CH3CrO2Cl2C6H5CHOCrOHCl22H2OC6H5CHO

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