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Q.

Ethanol is reacted with acidified K2Cr2O7. What is the product formed?

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a

CH3COOH

b

CCl3CHO

c

C2H6

d

C2H5OH

answer is B.

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Detailed Solution

C2H5OH + K2Cr2O7/H+CH3CHOCH3COOH

Ethanoic acid is produced by first oxidising ethanol to ethanal. Potassium dichromate is a potent oxidising agent, and when it reacts with ethanol, the orange-colored dichromate ion (IV) solution is transformed into a green Cr(III) ion solution. This reaction is used to identify alcohol in suspected inebriated drivers' breath.

Therefore, the correct option is option (B) CH3COOH

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