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Q.

Ethyl acetate is synthesized from ethanol and acetic acid in a non reacting solvent by the following reaction:
 CH3COOH(l)+C2H5OH(l)CH3COOC2H5(l)+H2O(l); K=2.2
If the reaction is set up taking [CH3CO2C2H5]=0.22M,[H2O]=0.10M, [CH3CO2H]=0.010M,[C2H5OH]=0.010M,

the changes which take place as the system attains equilibrium is/are

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a

Concentrations of both ethyl acetate and water decrease. 

b

Concentration of ethyl acetate decreases while that of water remains constant.

c

Concentrations of both ethanol and acetic acid increase. 

d

No change in concentrations of reactants as well as product as the given concentrations correspond to their equilibrium values.

answer is A, C.

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Detailed Solution

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Q=0.22×0.10.01×0.01=220

As  Q>K, the reaction moves in the backward direction to attain equilibrium.

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