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Q.

Ethyl acetate reacts with CH3MgBr to form

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a

Primary alcohol and an acid

b

Secondary alcohol

c

Tertiary alcohol

d

An acid

answer is B.

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Detailed Solution

Esters react with Grignard reagent to form tert -alcohols having at least two alkyl groups, introduced through Grignard reagent, identical, the third introduced through ester may be similar or different.

CH3COOC2H5+CH3MglH2OCH3COCH3

       (ii)H2O(i)CH3MglCH3C|OH|CH2CH3CH3

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